ABSTRACT New techniques for manufacturing of biomaterials using additive/substrate manufacturing such as melting laser sintering (SLM) or CAD/CAM milling use micrometric metal powders to build custom parts. CoCrMo alloys are commonly used as biomaterials due to biocompatibility, high corrosion resistance and good mechanical properties. In this work, Cr-Co-based powder was obtained by mechanical alloying of Cr-Co-Mo-W alloy, using different Ball/Powder-Ratios (BPR) and thermal treatments. The powders were deagglomerated and characterized by X-ray diffraction (XRD) and Scanning electron microscopy (SEM). Based on SEM micrographs, the particle size analysis was used to compare the particles spheroidizing degree, using Feret’s diameter. The XRD patterns shown Co(solid-solution) as crystalline phase. The results of particles size indicates a decrease of Feret’s diameter in BPR (Ball/Powder-Ratio) from 4:1 to 6:1 understanding that from this ratio there is no significant decrease of this relation but there is an average size increase with losses in morphological aspect. The comparison between atomized powders and powder developed in this work indicates that atomized products present relation close to one which indicates there is uniformity in the particles spherical shape. Comparing ground powders from 6:1 ratio (before and after thermal treatment) there is a considerable decrease of Feret’s diameter being it decreased from 1.75 to 1.4, an increase of about 46% in particles spheroidizing.

RESUMO O objetivo deste trabalho foi a recuperação de descartes de ZrO2(Y2O3) oriundos de laboratórios de próteses dentárias, a partir do seu reprocessamento. Os descartes de ZrO2(Y2O3) foram fragmentados, peneirados e calcinados a 900ºC. Pós com tamanho menor que 32μm foram prensados uniaxialmente a 100MPa e sinterizados em temperaturas entre 1400 e 1600ºC-120min. Análise de difração de raios X realizadas nos materiais calcinados indicaram a presença majoritária da fase ZrO2 tetragonal. Os compactos apresentaram densidade a verde próximo a 47% e as amostras sinterizadas tiveram sua densidade relativa variando entre 83,5% e 95%, para temperaturas de sinterização de 1400 e 1600ºC, respectivamente. Os resultados da análise de difração de raios X indicaram a presença da fase ZrO2 tetragonal, com dureza Vickers e tenacidade máxima obtidos para as amostras sinterizadas a 1600ºC, da ordem de 1100 HV e 5,7 MPa.m1/2 respectivamente.

ABSTRACT The objective was the recovery of ZrO2(Y2O3) discarded arising from dentistry prosthetic laboratories. ZrO2(Y2O3) were fragmented, sieved and calcined at 900°C. Powders with size less than 32μm were uniaxially pressed to 100MPa and sintered at temperatures between 1400 and 1600ºC-120min. X-ray diffraction analysis performed on the calcined material showed the predominant presence of tetragonal ZrO2 phase. The green compact had the density close to 47% and sintered samples had a relative density ranging between 83.5% and 95% for sintering temperatures of 1400 and 1600ºC, respectively. The analysis results of X-ray diffraction indicated the presence of the tetragonal ZrO2 phase, with maximum Vickers hardness and toughness obtained for the samples sintered at 1600ºC, of the order of 1100 HV and 5.7 MPa.m1/2 respectively.

ABSTRACT: High-frequency measurements of wind, and temperature were made during the dry season of 2008 to study the development of an internal boundary layer at the main Brazilian space launching centre, Centro de Lançamento de Alcântara at Alcântara, Maranhão, Brazil. Turbulence measurements taken at the coast, in two different points 227 m apart show different daily cycles of turbulent kinetic energy friction velocity (u *), and buoyancy flux w’ T ν'. Surface roughness change, surface heating change, and a gap in the natural vegetation seem to be the causes for the variation in these turbulent parameters. The mean wind cycle also shows distinct patterns. It seems that, first, internal boundary layers develop when the oceanic surface layer reaches the continent, and a second when the first internal boundary layer’s flow encounters the gap. A direct implication is that turbulence is not horizontally homogeneous and measurements taken at single places are not spatially representative. Knowing how turbulence varies spatially is necessary information to understand the diffusion of pollutants exhausted by rockets near the coast.

Neste trabalho analisam-se as características espectrais da turbulência atmosférica na região do Centro de Lançamento de Alcântara (CLA), que sofre a influência de uma falésia e da brisa marítima provinda do oceano, visando obter informações sobre a estrutura turbulenta do local. Determinaram-se os espectros das 3 componentes do vento (u, v e w) na camada limite superficial sobre esse terreno homogêneo, visando aplicações no Projeto e Desenvolvimento dos foguetes de sondagem e do Veículo Lançador de Satélite (VLS) realizado pelo IAE. Os dados foram coletados no mês de agosto do ano de 1999 através de um anemômetro sônico tridimensional. Também se obteve resultados envolvendo as relações σu/u*, σv/u* e σw/u*, todos condizentes com os previstos na literatura.

In this work is analyzed the spectral characteristics of atmospheric turbulence in the Alcântara Launching Center (CLA), which suffers the influence of a cliff and of the sea breeze coming from the ocean. The atmospheric spectra were determined for the 3 wind components (u, v, and w) in the superficial boundary layer, to be used for the Research and Developpment (R&D) of sounding rockets and Satellite Launch Vehicle (VLS) build by IAE. The data were collected during the month of August, 1999 using a 3D sonic anemometer. Results involving the σu/u*, σv/u* and σw/u* relations are obtained, and are all consistent with those reported in literature.